The Reaction of Dimethyl Sulfoxide-Phosphorus Oxychloride Complex with Dimethylaniline and Anisole
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چکیده
منابع مشابه
Quantitation of the hydroxyl radical by reaction with dimethyl sulfoxide.
This investigation was conducted to validate the use of dimethyl sulfoxide (DMSO) as a quantitative molecular probe for the generation of hydroxyl radicals (HO.) in aqueous systems. Reaction of HO. with DMSO produces methane sulfinic acid as a primary product, which can be detected by a simple colorimetric assay. To evaluate this method for estimating total HO. production, we studied three mode...
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15 صفحه اولSynthesis of Enaminones and Their Reaction with Dimethyl Acetylene Dicarboxylate
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Hexakis(dimethyl sulfoxide)scandium(III) iodide, [Sc(OS(CH(3))(2))(6)]I(3) contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) angstroms. EXAFS spectra yield a mean Sc-O bond distance of 2.09(1) angstroms for solvated scandium(III) ions in dimethyl sulfoxide solution, consistent with six-coordination. Raman and infrared absorption spectra have been re...
متن کاملDFT study of dimers of dimethyl sulfoxide in gas phase
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interactions between dimethyl sulfoxide (DMSO) dimers. The structures obtained have been analyzed with the Atoms in Molecules (AIMs) and Natural Bond Orbital (NBO) methodologies. Four minima were located on the potential energy surface of the dimers. Three types of interactions are observed, CH•••O, CH•••...
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1961
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.82.10_1423